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RAS Earth ScienceИзвестия Российской академии наук. Физика атмосферы и океана Izvestiya, Atmospheric and Oceanic Physics

  • ISSN (Print) 0002-3515
  • ISSN (Online) 3034-6487

OZONE PHOTOCHEMICAL PRODUCTION EFFICIENCY IN NEAR-SURFACE LAYER OVER BOREAL FORESTS OF CENTRAL AND SOUTHERN SIBERIA

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PII
S3034648725040047-1
DOI
10.7868/S3034648725040047
Publication type
Article
Status
Published
Authors
K. B. Moiseenko
  • Affiliation: Obukhov Institute of atmospheric physics RAS
A. V. Vasileva
  • Affiliation: Obukhov Institute of atmospheric physics RAS
I. B. Belikov
  • Affiliation: Obukhov Institute of atmospheric physics RAS
E. V. Berezina
  • Affiliation: Obukhov Institute of atmospheric physics RAS
M. Yu. Arshinov
  • Affiliation: Zuev Institute of atmospheric optics SB RAS
B. D. Belan
  • Affiliation: Zuev Institute of atmospheric optics SB RAS
Volume/ Edition
Volume 61 / Issue number 4
Pages
457-473
Abstract
Quantitative assessments of photochemical ozone production (P), ozone production efficiency (ΔP) with respect to odd oxygen NO (= NO + NO), and NO exponential lifetime (τ) are estimated from continuous measurements of near-surface mixing ratios of O, NO and NO at the regional stations of ZOTTO (Central Siberia) and Fonovaya (Southern Siberia) in a photochemical active period from March–September. We obtain the general functional forms P ≈ A·[NO], ΔP = A/(1 + B[NO]), τ = ΔP / A' uniformly valid for the range of the measured NO mixing ratios (0.2–2 ppb), where A' is a proportionality constant in a NO-limiting regime of ozone production, and coefficients A and B depend on the total OH reactivity and exact composition of the CO, CH, and higher hydrocarbons (RH) mixture. We show that atmospheric oxidation of ozone precursors including those emitted from local biogenic sources, along with regional NO emissions, provide an important regional source of O and sink for odd oxygen in the atmospheric boundary layer over boreal forests in the region of study.
Keywords
озон оксиды азота тропосферная фотохимия региональные эмиссии летучие органические соединения предшественники озона атмосферный пограничный слой
Date of publication
27.12.2024
Year of publication
2024
Number of purchasers
0
Views
16

References

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